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PHATE Research Group

Shamberger Lab

Texas A&M University College of Engineering

Papers


Patents

  1. P.J. Shamberger, “Nucleating Agent for Lithium Nitrate Trihydrate Thermal Energy Storage Medium.” U.S. Patent 8,703,258, issued April 22, 2014.

Select Publications

2023

  1. Y. Zhang, C. Fincher, R. Gurrola*, W. Serem, D. Zhao, J. Shin, S. Banerjee, K. Xie, P.J. Shamberger, M. Pharr. Strategic Texturation of VO2 Thin Films for Tuning Mechanical, Structural, and Electronic Couplings during Metal-Insulator Transitions, Acta Materialia, 242, 118478 (2023). doi: 10.1016/j.actamat.2022.118478
  2. M. Deckard*, D. Sharar, M. Fish, P.J. Shamberger, Phase Change Material Behavior in Finite Thickness Slabs Under a Step Response Heat. ASME J. Electron. Packag., 145(1), 011201 (2023) doi: 10.1115/1.4054651

2022

  1. P. Schofield, A. Bradicich*, R. Gurrola*, Y. Zhang, T.D. Brown, M. Pharr, P.J. Shamberger, S. Banerjee. Harnessing the Metal—Insulator Transition of VO2 in Neuromorphic Computing, Adv. Mater., 2205294 (2022). doi: 10.1002/adma.202205294
  2. A. Aryal, A. Bradicich*, E.T. Iverson, C.T. Long, Hsu-Cheng Chiang, J.C. Grunlan, P.J. Shamberger. Thermal conductivity of multilayer polymer-nanocomposite thin films, J Appl Phys, 132, 195104 (2022). doi: 10.1063/5.0102203
  3. A. Chakraborty, J. Noh, P.J. Shamberger, C. Yu. Unveiling Real-time Crystallization of Zinc Nitrate Hexahydrate Using Zinc Acetate Dihydrate Nucleator and Carboxymethyl Cellulose Thickener, Energy Storage, e417 (2022). doi: 10.1002/est2.417
  4. A. Hoe*, A. Tamraparni, C. Zhang, A. Elwany, J. Felts, P.J. Shamberger. Design of Radially Variant Phase Change Material Composites, Adv. Eng. Mater., 2200841 (2022). doi: 10.1002/adem.202200841
  5. A. Chakraborty, P.J. Shamberger, C. Yu. In-Operando Crystallization Study of Zinc Nitrate Hexahydrate Using Zinc Oxide Nucleators, Energy Storage, e372, (2022). doi: 10.1002/est2.372
  6. S.N. Lak, S. Ahmed*, P.J. Shamberger, E.B. Pentzer. Encapsulation of Hygroscopic Liquids via Polymer Precipitation in Non-aqueous Emulsions, J Colloid Interface Sci., 628(B), 605-613 (2022). doi: 10.1016/j.jcis.2022.08.083
  7. A. Hoe*, J. Felts, P.J. Shamberger. Numerical Evaluation of Thermal Energy Storage Rate in Planar and Cylindrical Phase Change Material Composites, J Energy Storage, 55(A), 105430 (2022). doi: 10.1016/j.est.2022.105430
  8. A. Chakraborty, J. Noh, R. Mach*, P.J. Shamberger, C. Yu. Thermal Energy Storage Composites with Preformed Expanded Graphite Matrix and Paraffin Wax for Long-term Cycling Stability and Tailored Thermal Properties, J Energy Storage, 52, 104856 (2022). doi: 10.1016/j.est.2022.104856
  9. P. Schofield, E.J. Braham, B. Zhang, J.L. Andrews, H. Drozdick, D. Zhao, W. Zaheer, R. Gurrola*, K. Xie, P.J. Shamberger, X. Qian, S. Banerjee, Decoupling the Metal—Insulator Transition Temperature and Hysteresis of VO2, Chem. Commun., 58, 6586-6589 (2022). doi: 10.1039/d2cc01599d
  10. S. Ahmed*, A. Hoe*, F. Alamo#, N. Turner#, P.J. Shamberger. Experimental Determination of High Energy Density Lithium Nitrate Hydrate Eutectics, J Energy Storage, 52, 104754 (2022). doi: 10.1016/j.est.2022.104754
  11. M. Shanks, C.M. Shoalmire*, M. Deckard*, K. Gohil, H. Lewis II, D. Lin, P.J. Shamberger, N. Jain, Design of Spatial Variability in Thermal Energy Storage Modules for Enhanced Power Density Applied Energy, Applied Energy, 314, 118966 (2022). doi: 10.1016/j.apenergy.2022.118966
  12. A. Hoe*, M.T. Barako, A. Tamraparni, C. Zhang, A. Elwany, J. Felts, P.J. Shamberger. Objective Oriented Phase Change Material Composite Heat Sink Design, Applied Thermal Eng., 209, 118235 (2022). doi: 10.1016/j.applthermaleng.2022.118235

2021

  1. A. Bradicich*, H. Clarke*, E.J. Braham, A. Yano*, D. Sellers, Sarbajit Banerjee, P.J. Shamberger. Probing Relaxation Dynamics and Stepped Domain Switching in Boron-Alloyed VO2, Advanced Electronic Materials, 8(3), 2100932 (2021). doi: 10.1002/aelm.202100932.
  2. K. Rajagopalan, P. Karimineghlani, X. Zhu, P.J. Shamberger, and S.A. Sukhishvili, Polymers in Molten Inorganic Salt Hydrates: Solubility and Gelation, J Mater. Chem, A, 9, 25892 (2021). doi: 10.1039/D1TA07842A.
  3. S. Chakravarty*, D.J. Sharar, P.J. Shamberger. Heterogeneous Nucleation of Gallium with Lattice-Matched Cubic Carbide and Nitride Phases, J. Appl. Phys, 130, 125107 (2021). doi: 10.1063/5.0060207.
  4. C.T. Long, R. Wang, C. Shoalmire*, D. Antao, P.J. Shamberger, J.C. Grunlan, Heat Shielding of Steel with Polymer-Clay Multilayer Thin Films, ACS Appl. Mater. Interfaces, 13(16), 19369-19376 (2021). doi: 10.1021/acsami.1c03781
  5. Y. Zhang*, C. Lago*, I. Karaman, P.J. Shamberger. Nucleation site potency distributions in thermoelastic martensitic transformation in Ni43Co7Mn39Sn11 particles, Phys. Rev. Mater., 5(2), 023401 (2021). doi: 10.1103/PhysRevMaterials.5.023401
  6. A. Ali, P.J. Shamberger, S. Vaddiraju. Thermal Conductivity of Mg2Si1-xSnx Nanowire Assemblies Synthesized using Solid-State Phase Transformation of Silicon Nanowires, Mater. Res. Express., 8(2), 025005 (2021). doi: 10.1088/2053-1591/abdf80
  7. C. Zhang, A. Banerjee, A. Hoe*, A. Tamraparni, J. Felts, P.J. Shamberger, A. Elwany. Design for laser powder bed additive manufacturing of AlSi12 periodic mesoscale lattice structures, Int. J. Adv. Manuf. Technol. (2021). doi: 10.1007/s00170-021-06817-w

2020

  1. A. Tamraparni, A. Hoe*, M. Deckard*, C. Zhang, P.J. Shamberger, A. Elwany, J. Felts. Design and optimization of lamellar phase change composites for thermal energy storage, Adv. Eng. Mtls., 2001052 (2020). doi: 10.1002/adem.202001052
  2. A. Yano*, H. Clarke*, D. Sellers, E.J. Braham, T.E.G. Alivio, S. Banerjee, P.J. Shamberger. Towards High-Precision Control of Transformation Characteristics in VO2 through Dopant Modulation of Hysteresis, J. Phys. Chem. C., 124(39), 21223-21231 (2020). doi: 10.1021/acs.jpcc.0c04952
  3. P.J. Shamberger, A. Hoe*, M. Deckard*, M. T. Barako.  Dynamics of Melting in a Slab under Harmonic Heating and Convective Cooling Boundary Conditions, J. Appl. Phys., 128, 105102 (2020).  doi: 10.1063/5.0016060
  4. Sellers, E. Braham, R. Villarreal, B. Zhang, A. Parija, T.D. Brown*, T. Alivio, H. Clarke*, L. De Jesus, L. Zuin, D. Prendergast, X. Qian, R. Arróyave, P.J. Shamberger, S. Banerjee. An Atomic Hourglass and Thermometer Based on Diffusion of a Mobile Dopant in VO2, J. Am. Chem. Soc., 142(36), 15513-15526 (2020). doi: 10.1021/jacs.0c07152
  5. H.P. de Bock, D. Huitink, P.J. Shamberger, J.S. Lundh, S. Choi, N. Niedbalski, L. Boteler.  A System to Package Perspective on Transient Thermal Management of Power Electronics, ASME J Electronics Packaging. 142(4), 041111-1-11 (2020). doi: 10.1115/1.4047474
  6. A. Tamraparni, P.J. Shamberger, J. Felts. Cyclic Stability of Lithium Nitrate Trihydrate in Plate Fin Heat Exchangers, Appl. Therm. Eng. 179, 115476 (2020). doi: 10.1016/j.applthermaleng.2020.115476
  7. A. Hoe*, M. Deckard*, A. Tamraparni, A. Elwany, J. Felts, P.J. Shamberger. Conductive Heat Transfer in Lamellar Phase Change Material Composites, Appl. Therm. Eng. 178, 115553 (2020). doi: 10.1016/j.applthermaleng.2020.115553
  8. T.D. Brown*, J.-H. Chen, E.J. Braham, S. Stadler, P.J. Shamberger. Dynamic Re-equilibration Controlled Multi-step Transformations in (Mn,Fe)2(P,Si) Alloys, J. Phys. D: Appl. Phys. 53(20), 205303 (2020). doi: 10.1088/1361-6463/ab768a
  9. T.D. Brown*, D. Galvan#, J. van Buskirk#, A. Mott, P.J. Shamberger. Effect of Carbide Formation on Phase Equilibria and Compositional Modulation of Transformation Properties in (Mn,Fe)2(P,Si) Alloys, J. Alloys Compounds, 830, 154532 (2020). doi: 10.1016/j.jallcom.2020.154532
  10. P.J. Shamberger, N. Bruno. Review of Metallic Phase Change Materials for High Heat Flux Transient Thermal Management Applications, Applied Energy, 258, 113955 (2020). doi: 10.1016/j.apenergy.2019.113955
  11. H. Clarke*, L. Deremo#, J. Anderson#, S. Ganguli, P.J. Shamberger. Conductive Filament Shape in HfO2 Electrochemical Metallization Cells Under a Range of Forming Voltages, Nanotechnology, 55(7), 075706 (2020). doi: 10.1088/1361-6528/ab53a9

2019

  1. Q. Li, C. Hu, H. Clarke*, M. Li, P.J. Shamberger, W. Wu, J. Yuan. Microstructure Defines the Electroconductive and Mechanical Performance of Plant-derived Renewable Carbon Fiber, Chemical Communications, 55, 12655-12658 (2019). doi: 10.1039/c9cc05016g
  2. Y. Zhang*, J. Billman#, P.J. Shamberger. Size Effects in Hysteresis of Electrochemically Deposited Ni-Mn-Sn Heusler Alloy Films, Acta Materialia, 180, 116-135 (2019). doi: 10.1016/j.actamat.2019.09.001
  3. K. Yazawa, P.J. Shamberger, T. Fisher. Ragone Relations for Thermal Energy Storage Technologies, Frontiers in Mech. Eng., 5, 29 (2019). doi: 10.3389/fmech.2019.00029

2018

  1. E. Emmons*, P.J. Shamberger. Corrosive Effect of Lithium Nitrate Trihydrate on Common Heat Exchanger Materials, Materials and Corrosion, 1-11 (2018) doi: 10.1002/maco.201810557
  2. Clarke, H.*, B. Carraway#, D. Sellers, E. Braham, S. Banerjee, R. Arróyave, P.J. Shamberger. Nucleation-controlled hysteresis in unstrained hydrothermal VO2 particles, Phys. Rev. Materials, 2, 103402 (2018) doi: 10.1103/PhysRevMaterials.2.103402
  3. Zhang, Y.*, P.J. Shamberger. Thick Film Ni0.5Mn0.5-xSnx Heusler Alloys by Multi-layer Electrochemical Deposition, Scientific Reports, 8, 11931 (2018) doi: 10.1038/s41598-018-29628-8
  4. Brown, T.D.*, T. Buffington#, P.J. Shamberger. Effects of Hysteresis and Brayton Cycle Constraints on Magnetocaloric Refrigerant Performance, J. Appl. Phys., 123(18), 185101 (2018). doi: 10.1063/1.5022467
  5. Braham, E., D. Sellers, Emmons*, R. Villarreal, H. Asayesh-Ardakani, N. Fleer, K. Farley, R. Shahbazian-Yassar, R. Arroyave, P.J. Shamberger, S. Banerjee. Modulating the Hysteresis of an Electronic Transition: Launching Alternative Transformation Pathways in the Metal—Insulator Transition of Vanadium(IV) Oxide, Chemistry of Materials, 30(1), 214-224 (2018) . doi: 10.1021/acs.chemmater.7b04203
  6. Shamberger, P.J., T. Fisher. Cooling Power and Characteristic Times of Composite Heatsinks and Insulants, J. Heat Mass Transfer, 117, 1205-1215 (2018). doi: 10.1016/j.ijheatmasstransfer.2017.10.085

2017

  1. Andrews, J.L., S. Singh, C. Kilcoyne, P.M. Marley, P.J. Shamberger, G. Sambandamurthy, S. Banerjee. Memristive response of a new class of hydrated vanadium oxide intercalation compounds, MRS Comm., 7(3), 634-641 (2017).  doi: 10.1557/mrc.2017.64
  2. Shamberger, P.J.. Y. Mizuno, A. Talapatra. Mixing and Electronic Entropy Contributions to Thermal Energy Storage in Low Melting Point Alloys,J. Appl. Phys., 122(2), 025105 (2017). doi: 10.1063/1.4990984.
  3. Karimineghlani, P., E. Emmons*, M. Green, P.J. Shamberger, and S. Sukhishvili. A Temperature-Responsive Polymer Matrix for Controlling Fluidity of an Inorganic Phase Change Material, J. Mater. Chem. A, 5, 12474-12482 (2017). doi: 10.1039/c7ta02897k
  4. Alivio, T.E.G., D. Sellers, H. Asayesh-Ardakani, E. Braham, G. Horrocks, K. Pelcher, R. Villareal, L. Zuin, P.J. Shamberger, R. Arróyave, R. Shahbazian-Yassar, S. Banerjee. A Post-Synthetic Route for Modifying the Metal—Insulator Transition of VO2 by Interstitial Dopant Incorporation, Mater. Chem.,  29(12), 5401-5412 (2017). doi: 10.1021/acs.chemmater.7b02029

2016

  1. Clarke, H.*, T. Brown*, J. Hu, R. Ganguli, A. Reed, A. Voevodin, P.J. Shamberger. Microstructure Dependent Filament Forming Kinetics in HfO2 Programmable Metallization Cells, Nanotechnology, 27(42), 425709 (2016). doi: 10.1088/0957-4484/27/42/425709
  2. Brown, T.D.*, I. Karaman, P.J. Shamberger. Impact of cycle-hysteresis interactions on the performance of giant magnetocaloric effect refrigerants, Materials Research Express, 3, 074001 (2016). doi: 10.1088/2053-1591/3/7/074001 **Emerging Investigators special edition**
  3. Shamberger, P.J.. J.L. Wohlwend, A.J. Roy, A.A. Voevodin. Investigating Grain Boundary Structures and Energetics of Rutile with Reactive Molecular Dynamics, J. Phys. Chem. C, 120(24). 13049-13062 (2016). doi: 10.1021/acs.jpcc.6b02695
  4. Shamberger, P.J.. Cooling Capacity Figure of Merit for Phase Change Materials, J. of Heat Transfer, 138(2), 024502 1-7 (2016). doi: 10.1115/1.4031252

2015

  1. Zhou, Y., E. Jungx, R. Arroyave, M. Radovic, P.J. Shamberger. Incorporating Research Experiences into an Introductory Materials Science Course, Int. J. Eng. Educ., 31(6A), 1491–1503 (2015).
  2. Brown, T.D.*, N. M. Bruno, J. Chen, I. Karaman, J. Ross, P.J. Shamberger. A Preisach-Based Nonequilibrium Methodology for Simulating Performance of Hysteretic Magnetic Refrigeration Cycles, JOM, 67(9), 2123-2132 (2015).  doi: 10.1007/s11837-015-1519-0
  3. Reed, A.*, P.J. Shamberger, C. Muratore, J.E. Bultman, J.J. Hu, A. A. Voevodin. Microstructure of ZnO Thin Films Deposited by HiPIMS, Thin Solid Films, 579, 30-37 (2015).  doi: 10.1016/j.tsf.2015.02.048
  4. Shamberger, P.J., M. O’Malley. Heterogeneous Nucleation of Thermal Storage Material LiNO3•3H2O from Stable Lattice-Matched Nucleation Catalysts, Acta Materialia, 84, 265-274 (2015).  doi: 10.1016/j.actamat.2014.10.051

2011-2014

  1. Muratore, C., J.J. Hu, M. A. Haque, J.E. Bultman, M.L. Jesperson, P.J. Shamberger, A. A. Voevodin. Continuous ultra-thin MoS2 films grown by low-temperature physical vapor deposition, Appl. Phys. Lett., 104, 261604 (2014).  doi: 10.1063/1.4885391
  2. Muratore, C., V. Varshney, J.J. Gengler, J.J. Hu, J.E. Bultman, T.M. Smith,  P.J. Shamberger, B. Qiu, X. Ruan, A. K. Roy, A. A. Voevodin. Cross-plane thermal properties of transition metal dichalcogenides, Appl. Phys. Lett., 102, 081604 (2013).  doi: 10.1063/1.4793203
  3. Shamberger, P.J., T. Reid. Thermophysical Properties of Potassium Fluoride Tetrahydrate from (243 to 348) K, J. Chem. Eng. Data, 58, 294-300 (2013).  doi: 10.1021/je300854w
  4. Amama, P.B., J.T. Grant, P.J. Shamberger, A.A.Voevodin, T.S. Fisher, Improved Dehydrogenation Properties of Ti-Doped LiAlH4: Role of Ti Precursors, J. Phys. Chem. C, 116, 21886-21894 (2012).  doi: 10.1021/jp307225w
  5. Wohlwend, J., P. Amama, P.J. Shamberger, V. Varshney, A. Roy, T. Fisher, Effects of Ti-Containing Additives on the Dehydrogenation Properties of LiAlH4: A Combined Computational and Experimental Study, J. Phys. Chem. C, 116, 22327-22335 (2012).  doi: 10.1021/jp3050109
  6. Shamberger, P.J., T. Reid. Thermophysical Properties of Lithium Nitrate Trihydrate from (253 to 353) K, J. Chem. Eng. Data, 57, 1404-1411 (2012).  doi: 10.1021/je3000469
  7. Amama, P.B., J.T. Grant, J.E. Spowart, P.J. Shamberger, A.A. Voevodin, and T.S. Fisher. Catalytic influence of Ni-based additives on the dehydrogenation properties of ball milled MgH2, J. Mater. Res. 26, 2725-2734 (2011).  doi: 10.1557/jmr.2011.230

2007-2010

  1. Shamberger, P.J., A.B. Pakhomov, K. Koyama, and F.S. Ohuchi. Deviation of the magnetization change from the structural phase transition temperature in polycrystalline Ni-Mn-Sn in low magnetic fields, Scripta Mater., 63(12), 1161-1164 (2010).  doi: 10.1016/j.scriptamat.2010.08.017
  2. Kazarinoff, P.D., P.J. Shamberger, F.S. Ohuchi, and C.K. Luscombe, OTFT performance of air-stable ester-functionalized polythiophenes, J. Mater. Chem., 20, 3040-3045 (2010).  doi: 10.1039/b927164c
  3. Wang, Y., O. Acton, G.G. Ting, T. Weidner, P.J. Shamberger, H. Ma, F.S. Ohuchi, D.G. Castner, and A. K.-Y. Jen, Effect of the phenyl ring orientation in the polystyrene buffer layer on the performance of pentacene thin-film transistors, Organic Electronics, 11(6), 1066-1073 (2010). doi: 10.1016/j.orgel.2010.03.006
  4. Acton, O., G.G. Ting, P.J. Shamberger, F.S. Ohuchi, H. Ma, and A. K.-Y. Jen, Dielectric Surface-Controlled Low-Voltage Organic Transistors via n-Alkyl Phosphonic Acid Self-Assembled Monolayers on High-k Metal Oxide, Applied Materials & Interfaces, 2(2), 511-520 (2010). doi: 10.1021/am9007648
  5. Shamberger, P.J., and F.S. Ohuchi. Hysteresis of the martensitic phase transition in magnetocaloric-effect Ni-Mn-Sn alloys, Phys. Rev. B, 79(14), 144407 (2009).  doi: 10.1103/PhysRevB.79.144407
  6. Briseno, A.L.,  S.C.B. Mannsfeld, P.J. Shamberger, F.S. Ohuchi, Z. Bao, S.A. Jenekhe, and Y. Xia. Self-assembly, molecular packing, and electron transport in n-type polymer semiconductor nanobelts, Chemistry of Materials, 20(14), 4712-4719 (2008).  doi: 10.1021/cm8010265
  7. Lu, C.Y., P.J. Shamberger, E. Yitamben, K. Beck, A. Joly, M.A. Olmstead, and F.S. Ohuchi. Laser and Electrical Current Induced Phase Transformation of In2Se3 Semiconductor Thin Film on Si (111), Applied Physics A., 93(1), 93-98 (2007). doi: 10.1007/s00339-008-4776-8
  8. Feaver, A., S. Sepehri, P. Shamberger, A. Stowe, T. Autrey, and G. Cao. Coherent Carbon Cryogel-Ammonia Borane Nanocomposites for H2 Storage, J. Phys. Chem. B, 111(26), 7469-7472 (2007).  doi: 10.1021/jp072448t

2005-2007

  1. Vazquez, J., P.J. Shamberger, and J.E. Hammer. Plutonic Xenoliths Reveal the Timing of Magma Evolution at Hualalai and Mauna Kea, Hawaii, Geology, 35(8), 695-698 (2007). doi: 10.1130/G23495A.1
  2. Shamberger, P.J., and M. O. Garcia. Geochemical modeling of magma mixing and magma reservoir volumes during early episodes of Kilauea Volcano’s Pu‘u ‘O‘o eruption. Bull. Volc., 69(4), 345-352 (2007). doi: 10.1007/s00445-006-0074-5
  3. Shamberger, P.J., and J.E. Hammer. Leucocratic & Gabbroic Xenoliths from Hualalai Volcano, Hawai‘i. J. Petrology, 47(9), 1785-1808 (2006). doi: 10.1093/petrology/egl027
  4. Hammer, J.E., M. Coombs, P.J. Shamberger, and J.-I. Kimura. Submarine sliver in North Kona: A window into the early magmatic and growth history of Hualalai Volcano, Hawaii.  J. Volcanol. Geotherm. Res., 151(1-3), 157-188 (2006). doi: 10.1016/j.jvolgeores.2005.07.028

* Undergraduate Student under the supervision of Shamberger

# Graduate Student under the supervision of Shamberger

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  • Dynamically Tunable Thermal Energy Storage
  • Thermal Energy Storage for Building Efficiency
  • Transient Thermal Management for Electric Machines
  • Neuromorphic Materials Systems
  • Nucleation in Reversible Phase Transformations
  • Design of Composite Phase Change Materials

Latest News

  • PHATE lab presents at Gordon Research Conference January 13, 2023
  • Rebeca Gurrola passes prelim! December 17, 2022
  • Seeking Prospective Grad Students in Energy Storage / Neuromorphic Materials November 21, 2022
  • ICFSMA 2023: Join us in College Station, TX! November 15, 2022
  • Congrats to TAMU EFRC team! September 5, 2022

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